Understanding Plant Nutrition: Irrigation Water Alkalinity & pH

Understanding Plant Nutrition: Irrigation Water Alkalinity & pH

Water quality is a key factor affecting pH and nutritional management in container-grown crops. Understanding a few technical details about water quality will help you improve nutrient management appropriate for your own greenhouse. In this article, we will discuss the difference between water pH and alkalinity. We will also discuss how to interpret water pH and alkalinity results, and adjust your pH management strategies accordingly. 

pH And Alkalinity Are Two Different Aspects Of Water Quality

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The term pH is a direct measurement of the balance between acidic hydrogen ions (H+) and basic hydroxide ions (OH-), and can be measured with a pH meter. The pH of a solution can range between 0 (very acidic) and 14 (very basic). At a pH of 7.0, the concentrations of H+ and OH- are equal, and the solution is said to be neutral. When the pH is above 7.0, the concentration of OH- is higher than H+, and the solution is said to be basic or alkaline (not to be confused with alkalinity). When the solution is below 7.0, the concentration of H+ is higher than OH-, and the solution is said to be acidic.

Alkalinity is a measure of how much acid it takes to lower the pH below a certain level, also called acid-buffering capacity. Alkalinity is not a specific ion, but rather includes the concentration of several ions that affect acid-buffering capacity.

Under most conditions, the ions that have the greatest effect on alkalinity are bicarbonates like calcium, magnesium or sodium bicarbonate and, to a lesser extent, carbonates like calcium or sodium. Several other ions (like hydroxides or sulfides) also can contribute to alkalinity, but their concentration in most irrigation water is usually so low that they can be ignored. 

Units Of Measurement For Total Alkalinity

In a water sample, the concentration of all of the ions that make up the alkalinity term are combined and reported as equivalents of calcium carbonate, CaCO3, which is the main component of lime. Alkalinity can therefore be thought of as the “liming content” of the water.

The concentration of alkalinity (or any other plant nutrient) can be expressed a number of different ways:

1) Parts per million (ppm or mg/liter): A weight per weight ratio. One part per million is equivalent to one unit of something dissolved in a million units of something else. In the case of anything dissolved in water, 1 ppm is equal to 1 mg/liter.

2) Milliequivalent (mEq/liter): A chemistry term that is not only dependent on a materials concentration, but also on its molecular weight and charge. In the case of alkalinity, 50 ppm (or mg/liter) CaCO3 equals 1 mEq/liter CaCO3. Sometimes, the concentration of bicarbonates is also reported on a water test from a commercial laboratory. In most cases, bicarbonate makes up most of the alkalinity. The relationship is 61 ppm bicarbonate equals 1 mEq total alkalinity.

Water Alkalinity Has A Big Effect On Substrate pH

When it comes to managing the pH of a substrate, the alkalinity concentration has a much greater effect than does water pH. Alkalinity (calcium bicarbonate, magnesium bicarbonate and sodium bicarbonate) and limestone (calcium and magnesium carbonate) react similarly to limestone when added to a container media. And just like too much limestone, the use of irrigation water containing high levels of alkalinity can cause the pH of the substrate to increase above acceptable levels for healthy plant growth.

For example, a limestone incorporation rate of 5 pounds per cubic yard will supply approximately 100 mEq of limestone per 6-inch (15-cm) pot. Applying 16 fluid ounces (0.5 liters) of water containing 250 ppm alkalinity to that 6-inch pot will supply about 2.5 mEq of lime. That does not sound like much until you consider that after 10 irrigations, you have effectively increased the limestone incorporation rate by 25 percent.

To compare the effect of water pH or alkalinity on the ability to raise pH (or neutralize acid) in a medium, 50 ppm alkalinity (which is a low alkalinity) would be similar to having a water with pH 11 (i.e. an extremely high pH). A water with a pH of 8.0 would have the same effect on substrate pH as an alkalinity concentration of only 0.05 ppm (i.e., almost nothing).

Don’t ignore water pH, though. Water pH is still important for crop management because it affects the solubility of fertilizers and the efficacy of insecticides and fungicides before you apply it to the crop (Figure 2). Generally, the higher the water pH, the lower the solubility of these materials. 

Minimizing The Effects Of High Alkalinity

The common problems associated with high alkalinity result from its tendency to increase media pH. Since the solubility of micronutrients (particularly iron) decreases as media pH increases, the use of high alkalinity water often results in micronutrient deficiency in the crop (Figure 2).

The most common method for minimizing the “liming effect” of high alkalinity is to neutralize it by adding a strong mineral acid (usually sulfuric acid or phosphoric acid) directly to the irrigation water. The acid causes the water pH to decrease, which neutralizes some of the alkalinity. All of the alkalinity has been neutralized when the pH of the water reaches 4.5. For more specific recommendations on how much acid is needed to neutralize a specific amount of alkalinity, you can download the “Acid Addition Calculator” from Purdue University and North Carolina State University at www.ces.ncsu.edu/depts/hort/floriculture/software/alk.html.

Another option for alkalinity control is to use acidic fertilizers. Fertilizers high in ammoniacal nitrogen produce an acidic reaction when added to a container media, which can be used to neutralize the liming effect of water alkalinity. For example, 20-20-20 (69 percent NH4-N) has enough acidity to be used with water containing around 200 ppm alkalinity water without further acidification.

There are several drawbacks to using fertilizer for alkalinity control. Fertilizers high in ammoniacal nitrogen may cause excessive growth and are not effective when the temperature of the substrate is less than 60ËšF. In addition, you lose flexibility because you can only choose commercial fertilizers based on ammonium content. For example, fertilizers that contain more than 40 percent ammoniacal nitrogen do not contain calcium or other key nutrients. 

Low Alkalinity Effects

Not everybody has irrigation water with high alkalinity. In one study from Michigan State University, about 30 percent of the irrigation water tested had alkalinity levels below 40 ppm without any acidification. Even in areas where high alkalinity is considered normal, some growers have switched to low alkalinity sources such as reverse osmosis purified water or rain water.

The primary problem associated with low alkalinity water is a tendency for substrate pH to drop over time, which can cause micronutrient toxicity problems (Figure 3). Low media pH problems are often a result of fertilizer selection. Fertilizers high in ammoniacal nitrogen are acidic, and without any alkalinity in the water to balance the reaction (resist lowering of pH), acidic fertilizers will tend to drive the substrate pH down over time.

Understanding a few technical details about water alkalinity can help you improve pH management. However, irrigation water can affect plant nutrition in more ways than just media pH. In next month’s article, we will discuss irrigation water as a nutrient source.

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Avatar for Anonymous Anonymous says:

You might have a mistake explaining the term ppm.
In my opinion 1 ppm is one unit of something disolved in 999,999 units of something else.
the whole solution (The solvent and the disolved) will contain 1000,000 unites.
Of course, when you calculate only 100 0r 200 ppm in fertilizers the diference could be ignored, but,,if you calculate other chemicals that could be very significant especially when you use plant regulators of hormones in the water irrigation.

Avatar for Anonymous Anonymous says:

You might have a mistake explaining the term ppm.
In my opinion 1 ppm is one unit of something disolved in 999,999 units of something else.
the whole solution (The solvent and the disolved) will contain 1000,000 unites.
Of course, when you calculate only 100 0r 200 ppm in fertilizers the diference could be ignored, but,,if you calculate other chemicals that could be very significant especially when you use plant regulators of hormones in the water irrigation.

Avatar for Clyde Cozad Clyde Cozad says:

I live in the country and was raised on a farm. We had cattle and raised alfafa for the critters and corn, wheat, milo and or oats as row crops. We didn’t irrigate. We just hoped we would get timely rains to do the job. Some times we were lucky and sometimes we weren’t. Anyway, water alkalinity and ph weren’t important since we couldn’t control either even if we wanted to. However, on our little five acre plot, and a wife who was raised vegetarial, we have and enjoy a rather large organic garden. We are also fortunate to have neighbors who have riding horses and a good supply of horse manure for our use as a natural fertalizer. My explination of an organic garden is that we get to keep and can what the buggs don’t get! Anyway, we also have a hot tub which requires water ballance and chemicals to make the water feel like water. Our water comes from
our 175 foot well. I took a sample of the well water to our hot tub chemical supplier for testing. The total alkalinity measured 225 which is very high, hot tub wise. acceptable hot tub levels indicate 80 to 120 ppm. Now, back to the garden, which I of course we drink, cook with, bathe in, and irrigate with. Reading this article, it seems to me I need to find a way to reduce the alkalinity to facilitate a bumper crop for us and the buggs. Finally, my question, how do I do that while running copious amounts of water on our vegitables?

Avatar for James James says:

If it were me, I would do it with my fertization program. I would use barely decomposed chicken manure (high in non-nitrate type nitrogen) or barely decomposed horse manure, along with boosts of ammoniacal type nitrogen fertizers. If you use a boost of 20-20-20 soluble food, it would lower that ph also. Id go easy on these suggestions the 1st year, and if good results, go heavier and find a happy medium. But best if you got a ph tester and/or test kit and keep track of your progress.

Avatar for Troy Troy says:

how can irrigating effect plant nutrients